Reactivity and Mechanism in Organic Chemistry - Hendrik Zipse - Books - Royal Society of Chemistry - 9781839167430 - September 16, 2022
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Hendrik Zipse
Reactivity and Mechanism in Organic Chemistry

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Completely revised and updated, this 2nd Edition of Reactivity and Mechanism in Organic Chemistry is an ideal introduction to the quantitative description of organic reactivity for students in undergraduate and masters chemistry programmes. The book proceeds logically from qualitative molecular orbital theory as a tool for the description of bonding phenomena to combining this with thermochemical data to rationalise concepts such as molecular strain and hyperconjugation. Next, transition state theory, for examining organic reactivity phenomena, is introduced and its relation to energy surfaces and simple rate equations is discussed. On this basis more specific reactivity concepts commonly used in organic chemistry are explored such as the Bell-Evans-Polanyi principle, Marcus theory, HSAB principle, Hammett correlations, the Mayr-Patz equation, and FMO theory. How these reactivity models are applied is demonstrated for pericyclic reactions and selected rearrangement reactions involving transient intermediates such as radicals, diradicals, or carbocations, and for reactions involving classical electrophile/nucleophile combinations.

Media Books     Paperback Book   (Book with soft cover and glued back)
Released September 16, 2022
ISBN13 9781839167430
Publishers Royal Society of Chemistry
Pages 218
Dimensions 150 × 220 × 10 mm   ·   317 g
Language English  

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