S Sulfur-Nitrogen Compounds: Part 10a: Compounds with Sulfur of Oxidation Number II - Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition - Norbert Baumann - Books - Springer-Verlag Berlin and Heidelberg Gm - 9783662063538 - October 3, 2013
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Norbert Baumann
S Sulfur-Nitrogen Compounds: Part 10a: Compounds with Sulfur of Oxidation Number II - Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition Eighth Edition 1994 edition

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The present volume describes acyclic Sulfur-nitrogen compounds with sulfur of the oxida­ tion number II. The first chapter deals with sulfur imide (S=NH), N-organyl-sulfur imides (S=NR, R = or­ ganyl), and metal complexes of sulfur imides. N-Organyl-sulfur imides have not been isolated, but they can be trapped, for example, by cycloaddition and stabilized by coordination to transi­ tion metals. 11 The following chapter present a detailed survey of other 8 -N compounds with one­ coordinate sulfur, e.g., dithionitrous acid (S=N-SH) and derivatives, the salts of the dithionitryl ion (1 +) ([S=N=S]+), and N-thionitroso-diorganyl-amines (S=NNR , R = organyl). Only the reac­ 2 tions of [S=N=S]+ AsF5, among the known [S=N=S]+ salts, have been extensively studied. Cycloadditions with alkenes and triple bonded compounds produce 1 ,3,2-dithiazolium salts and their derivatives. S=NN(CH )z and S=NN(C H )z form transition metal complexes. The 3 6 5 Iigand is coordinated via the S atom in a monodentate manner.

324 pages, 1 colour illustrations, biography

Media Books     Paperback Book   (Book with soft cover and glued back)
Released October 3, 2013
ISBN13 9783662063538
Publishers Springer-Verlag Berlin and Heidelberg Gm
Pages 324
Dimensions 178 × 254 × 19 mm   ·   669 g
Language English  
Contributor Alfons Kubny

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