S Sulfur-Nitrogen Compounds: Compounds with Sulfur of Oxidation Number IV - Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition - Norbert Baumann - Books - Springer-Verlag Berlin and Heidelberg Gm - 9783662063651 - October 3, 2013
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Norbert Baumann
S Sulfur-Nitrogen Compounds: Compounds with Sulfur of Oxidation Number IV - Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition Eighth Edition 1991 edition

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PF3, (CH3)3SiCl -> (CH3)3SiF, and RC(O) Cl -> RC(O) F. Others include the conversion of (C6H5)3P into (C6H5)3PF2 and of (R3NC(S) S)2 into R2NCF3, R=alkyl. In organic chemistry, fluorides are easily accessible from alcohols, geminal fluorides RR'CF2 from the respective aldehydes or ketones, and acyl fluorides RC(O) F from carboxylic acides by using DAST. Because DAST is easy to handle and gives clean reactions in syntheses, this Gmelin volume devotes much space to the description of the chemical and physical properties od DAST.

487 pages, 2 black & white illustrations, biography

Media Books     Paperback Book   (Book with soft cover and glued back)
Released October 3, 2013
ISBN13 9783662063651
Publishers Springer-Verlag Berlin and Heidelberg Gm
Pages 487
Dimensions 178 × 254 × 27 mm   ·   986 g
Language English  
Editor Baumann, Norbert
Editor Fachmann, Hans-Jurgen
Editor Heibel, Brigitte

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